Random Thoughts VI: The Undiscovered Country

Postby Bucky » Mon May 19, 2008 09:36:18

phatj wrote:
td11 wrote:hmm, i think you're talking about bond dissociation energies-- the O-H bond has a much higher dissociation energy than does the C-H bond.

It's been a long time since I took chemistry or physics, but it sounds like what Bucky is describing violates the Law of Conservation of Energy. You can't convert water into hydrogen (and oxygen) without putting as much energy into it as you'd get back by burning the resultant hydrogen.


That's what all the pundits are saying. It's all about the viability of a self-sustaining chemical chain reaction such as the phenomeon of combustion. Theory being, the energy is in there (such as with carbon based fuels); it's just a matter of getting it out.

Bucky
BSG MVP
BSG MVP
 
Posts: 58018
Joined: Fri Dec 29, 2006 19:24:05
Location: You_Still_Have_To_Visit_Us

Postby TenuredVulture » Mon May 19, 2008 10:10:21

Bucky wrote:
phatj wrote:
td11 wrote:hmm, i think you're talking about bond dissociation energies-- the O-H bond has a much higher dissociation energy than does the C-H bond.

It's been a long time since I took chemistry or physics, but it sounds like what Bucky is describing violates the Law of Conservation of Energy. You can't convert water into hydrogen (and oxygen) without putting as much energy into it as you'd get back by burning the resultant hydrogen.


That's what all the pundits are saying. It's all about the viability of a self-sustaining chemical chain reaction such as the phenomeon of combustion. Theory being, the energy is in there (such as with carbon based fuels); it's just a matter of getting it out.


But aren't carbon based fuels really just stored solar energy from millions of years ago? That is, the sun converted CO2 and H2O into hydrocarbons, and when we burn fossil fuels, we're really just releasing solar energy.
Be Bold!

TenuredVulture
You've Got to Be Kidding Me!
You've Got to Be Kidding Me!
 
Posts: 53243
Joined: Thu Jan 04, 2007 00:16:10
Location: Magnolia, AR

Postby phatj » Mon May 19, 2008 11:26:41

TenuredVulture wrote:
Bucky wrote:
phatj wrote:
td11 wrote:hmm, i think you're talking about bond dissociation energies-- the O-H bond has a much higher dissociation energy than does the C-H bond.

It's been a long time since I took chemistry or physics, but it sounds like what Bucky is describing violates the Law of Conservation of Energy. You can't convert water into hydrogen (and oxygen) without putting as much energy into it as you'd get back by burning the resultant hydrogen.


That's what all the pundits are saying. It's all about the viability of a self-sustaining chemical chain reaction such as the phenomeon of combustion. Theory being, the energy is in there (such as with carbon based fuels); it's just a matter of getting it out.


But aren't carbon based fuels really just stored solar energy from millions of years ago? That is, the sun converted CO2 and H2O into hydrocarbons, and when we burn fossil fuels, we're really just releasing solar energy.

That's quite true, but what Bucky is talking about is water, not carbon-based fuels. And the energy isn't "in there" -- that's why water is the product of an exothermic reaction.

You can take the water that results from burning hydrogen and break it down into hydrogen and oxygen again, but you have to put in as much energy as you get out by burning it. Otherwise, you could create a perpetual motion machine.
they were a chick hanging out with her friends at a bar, the Phillies would be the 320 lb chick with a nose wart and a dick - Trent Steele

phatj
Moderator
 
Posts: 20683
Joined: Thu Dec 28, 2006 23:07:06
Location: Andaman Limp Dick of Certain Doom

Postby TenuredVulture » Mon May 19, 2008 12:33:43

phatj wrote:
TenuredVulture wrote:
Bucky wrote:
phatj wrote:
td11 wrote:hmm, i think you're talking about bond dissociation energies-- the O-H bond has a much higher dissociation energy than does the C-H bond.

It's been a long time since I took chemistry or physics, but it sounds like what Bucky is describing violates the Law of Conservation of Energy. You can't convert water into hydrogen (and oxygen) without putting as much energy into it as you'd get back by burning the resultant hydrogen.


That's what all the pundits are saying. It's all about the viability of a self-sustaining chemical chain reaction such as the phenomeon of combustion. Theory being, the energy is in there (such as with carbon based fuels); it's just a matter of getting it out.


But aren't carbon based fuels really just stored solar energy from millions of years ago? That is, the sun converted CO2 and H2O into hydrocarbons, and when we burn fossil fuels, we're really just releasing solar energy.

That's quite true, but what Bucky is talking about is water, not carbon-based fuels. And the energy isn't "in there" -- that's why water is the product of an exothermic reaction.

You can take the water that results from burning hydrogen and break it down into hydrogen and oxygen again, but you have to put in as much energy as you get out by burning it. Otherwise, you could create a perpetual motion machine.


That's what I was trying to get at. The energy that is "in there" isn't really the same. It's why sugar has calories, while water has none.

Now, if you could somehow do photosynthesis, you could make your own hydrocarbons from CO2 and H2O.
Be Bold!

TenuredVulture
You've Got to Be Kidding Me!
You've Got to Be Kidding Me!
 
Posts: 53243
Joined: Thu Jan 04, 2007 00:16:10
Location: Magnolia, AR

Postby Woody » Mon May 19, 2008 14:51:28

If you uses Papyrus or Comic Sans as an e-mail font, you should be fired
you sure do seem to have a lot of time on your hands to be on this forum? Do you have a job? Are you a shut-in?

Woody
BSG MVP
BSG MVP
 
Posts: 52472
Joined: Thu Dec 28, 2006 17:56:45
Location: captain of the varsity slut team

Postby phatj » Mon May 19, 2008 14:57:49

Woody wrote:If you uses Papyrus or Comic Sans as an e-mail font, you should be fired

Papyrus? Seriously?
they were a chick hanging out with her friends at a bar, the Phillies would be the 320 lb chick with a nose wart and a dick - Trent Steele

phatj
Moderator
 
Posts: 20683
Joined: Thu Dec 28, 2006 23:07:06
Location: Andaman Limp Dick of Certain Doom

Postby Bucky » Mon May 19, 2008 14:58:31

There is the equivalent energy of 14 barrels of oil in one Papyrus

Bucky
BSG MVP
BSG MVP
 
Posts: 58018
Joined: Fri Dec 29, 2006 19:24:05
Location: You_Still_Have_To_Visit_Us

Postby Houshphandzadeh » Mon May 19, 2008 16:30:10

I went to Dave and Buster's Saturday and it was so lame that I forgot all about it until I noticed this stupid Powercard in my wallet.

Houshphandzadeh
BSG MVP
BSG MVP
 
Posts: 64362
Joined: Thu Dec 28, 2006 19:15:12
Location: nascar victory

Postby Phight On! » Mon May 19, 2008 17:21:13

I've made it into someone's (slowhand) signature.

I can now die in peace.
"Listen here you beatiful b***h, I'm gonna fuck you up with some truth." - Kenny Powers

Phight On!
BSG MVP
BSG MVP
 
Posts: 4297
Joined: Fri Dec 29, 2006 14:30:43
Location: The Reservation of the Smack-A-Ho Tribe

Postby Woody » Mon May 19, 2008 18:09:16

phatj wrote:
Woody wrote:If you uses Papyrus or Comic Sans as an e-mail font, you should be fired

Papyrus? Seriously?


srsly.
you sure do seem to have a lot of time on your hands to be on this forum? Do you have a job? Are you a shut-in?

Woody
BSG MVP
BSG MVP
 
Posts: 52472
Joined: Thu Dec 28, 2006 17:56:45
Location: captain of the varsity slut team

Postby Woody » Mon May 19, 2008 18:13:02

The mexicans that live behind me have a beagle that won't.stop.barking.

I"m about to become a Republican
you sure do seem to have a lot of time on your hands to be on this forum? Do you have a job? Are you a shut-in?

Woody
BSG MVP
BSG MVP
 
Posts: 52472
Joined: Thu Dec 28, 2006 17:56:45
Location: captain of the varsity slut team

Postby Phight On! » Mon May 19, 2008 18:47:27

Does anybody else go to the store (which is like 2 minutes away) to buy new wifebeaters instead of doing a few loads of laundry?

Wife calls it laziness.

I call it genius.
"Listen here you beatiful b***h, I'm gonna fuck you up with some truth." - Kenny Powers

Phight On!
BSG MVP
BSG MVP
 
Posts: 4297
Joined: Fri Dec 29, 2006 14:30:43
Location: The Reservation of the Smack-A-Ho Tribe

Postby Woody » Mon May 19, 2008 18:54:23

Never in my life have I been so excited to get a B+............................................
you sure do seem to have a lot of time on your hands to be on this forum? Do you have a job? Are you a shut-in?

Woody
BSG MVP
BSG MVP
 
Posts: 52472
Joined: Thu Dec 28, 2006 17:56:45
Location: captain of the varsity slut team

Postby td11 » Mon May 19, 2008 18:58:58

Woody wrote:Never in my life have I been so excited to get a B+............................................
td11
Plays the Game the Right Way
Plays the Game the Right Way
 
Posts: 35802
Joined: Fri Dec 29, 2006 03:04:40

Postby lethal » Mon May 19, 2008 19:56:05

I got into a fist fight in the middle of 6th avenue after work today.

lethal
BSG MVP / ninja
BSG MVP / ninja
 
Posts: 10795
Joined: Thu Dec 28, 2006 18:00:11
Location: zOMGWTFBBQ?

Postby ReadingPhilly » Mon May 19, 2008 20:03:10

lethal wrote:I got into a fist fight in the middle of 6th avenue after work today.


This needs its own thread.

ReadingPhilly
You've Got to Be Kidding Me!
You've Got to Be Kidding Me!
 
Posts: 59729
Joined: Tue Apr 10, 2007 15:32:14

Postby ace » Mon May 19, 2008 20:06:36

The day that a cable bill for $171 shows up in my mailbox is not the day that my cable box should decide to stop at channel 21.

And yes, they tried to reset the signal. They said to give it an hour. They lie, and I hate them.

ace
There's Our Old Friend
There's Our Old Friend
 
Posts: 560
Joined: Thu Dec 28, 2006 21:17:23

Postby Woody » Mon May 19, 2008 20:30:28

Sick lethal on 'em, ace.
you sure do seem to have a lot of time on your hands to be on this forum? Do you have a job? Are you a shut-in?

Woody
BSG MVP
BSG MVP
 
Posts: 52472
Joined: Thu Dec 28, 2006 17:56:45
Location: captain of the varsity slut team

Postby jerseyhoya » Mon May 19, 2008 20:36:48

If I didn't have a drinking problem, following the Phillies would really suck

jerseyhoya
BSG MVP
BSG MVP
 
Posts: 97408
Joined: Fri Sep 07, 2007 21:56:17

Postby ace » Mon May 19, 2008 20:36:55

ninja for hire?

ace
There's Our Old Friend
There's Our Old Friend
 
Posts: 560
Joined: Thu Dec 28, 2006 21:17:23

PreviousNext